陆相页岩内物质转移对储集性的调控机制——以渤海湾盆地牛庄洼陷古近系沙四段上亚段页岩为例

Regulation mechanisms of material transfer within continental shale on reservoir properties: a case study of shale from upper submember of fourth member of Paleogene Shahejie Formation, Niuzhuang Subsag, Bohai Bay Basin

  • 摘要: 陆相页岩油气是我国油气增储上产的重要领域,然而传统宏观—岩心尺度研究难以揭示纹层内部物质迁移与孔隙演化的关系。以渤海湾盆地济阳坳陷东营凹陷牛庄洼陷古近系沙河街组四段上亚段陆相页岩为研究对象,综合X射线衍射、氩离子抛光—场发射扫描电镜—能谱分析、岩石薄片显微观察等微观分析手段,揭示了其成岩演化特征及物质转移对储集性的调控机制。研究发现,牛庄洼陷沙四上亚段强超压页岩储集空间形成受“超压流体—成岩矿物”协同控制。早—中成岩阶段叠锥—柱纤方解石形成期,δ18O负漂移3.56‰~5.47‰,对52.14~76.17 MPa超压增压具有明显响应。黄—蓝白荧光烃类包裹体和伴生盐水包裹体均一温度指示油气捕获早于超压盐水,盐度倒置现象反映了长石溶蚀供盐与碳酸盐胶结耗盐过程,证实了生烃对孔隙流体的增压作用。超压流体通过“方解石溶蚀—重结晶扩喉”与“黏土转化—石英支撑”双机制构建纳米—微米级孔缝网络。在超压流体环境中,4类不同成因的方解石表现为“同生泥晶→成岩重结晶→成岩叠锥—柱纤→裂缝成岩”的δ18O漂移路径,导致自封闭体系内12C、16O优先出溶,δ13C、δ13O同步负偏。有机酸优先溶蚀泥晶方解石形成小于10 nm的孔隙,方解石重结晶为柱纤状亮晶结构,孔径扩至20~50 nm。页岩中烃类流体易于在方解石、白云石等颗粒边缘聚集形成微米级粒缘缝,黏土矿物转化产生的硅质在这些微裂缝和孔隙发育区域优先成核沉淀,结晶为粒径5~30 μm、自形—半自形的自生石英晶体,产生“支撑—增刚—保孔”协同效应。区别于传统硅质充填孔隙机制,研究提出黏土转化硅质在粒缘缝中沉淀形成自生石英,从而增强了储层微观孔缝的稳定性。

     

    Abstract: Continental shale oil and gas are important areas for increasing oil and gas reserves and production in China. However, traditional macroscopic-to-core scale studies are insufficient to reveal the relationship between material migration within laminae and pore evolution. Taking the continental shale from the upper submember of the fourth member of the Paleogene Shahejie Formation in the Niuzhuang Subsag, Dongying Sag, Jiyang Depression, Bohai Bay Basin as the study object, this study employed microscopic analytical methods such as X-ray diffraction, argon ion polishing-field emission scanning electron microscopy-energy spectrum spectroscopy, and rock thin-section microscopic observation to reveal the diagenetic evolution characteristics and the regulatory mechanisms of material transfer on reservoir properties. The study found that the formation of reservoir spaces in the strongly overpressured shale of the upper Es4 submember in the Niuzhuang Subsag was synergistically controlled by "overpressured fluid-diagenetic minerals". During the formation period of cone-in-cone and columnar-fibrous calcite in the early to middle diagenetic stage, a negative shift of δ18O by 3.56%-5.47‰ was observed, showing a distinct response to the overpressure increase of 52.14-76.17 MPa. The homogenization temperatures of yellow-blue-white fluorescent hydrocarbon inclusions and associated brine inclusions indicated that hydrocarbon entrapment occurred earlier than the overpressured brine. The phenomenon of salinity inversion reflected the process of salt supply from feldspar dissolution and salt consumption by carbonate cementation, confirming the pressurizing effect of hydrocarbon generation on pore fluids. Overpressured fluids constructed a nano-micron pore-fracture network through the dual mechanisms of "calcite dissolution-recrystallization throat expansion" and "clay mineral transformation-quartz cementation support". In the overpressured fluid environment, four types of calcite with different origins exhibited a δ18O shift path of "syngenetic micrite → diagenetic recrystallization → diagenetic cone-in-cone and columnar-fibrous calcite → fracture filling", leading to the preferential exsolution of 12C and 16O within the self-enclosed system and synchronous negative shifts in δ13C and δ18O. Organic acids preferentially dissolved micritic calcite to form pores smaller than 10 nm, and the recrystallization of calcite into a columnar-fibrous sparry structure expanded pore diameters to 20-50 nm. Hydrocarbon fluids in shale tended to accumulate at the edges of grains such as calcite and dolomite, forming micron-scale intergranular fractures. Silica derived from clay mineral transformation preferentially nucleated and precipitated in these areas where microfractures and pores developed, crystallizing into authigenic quartz crystals with particle sizes of 5-30 μm and euhedral-subhedral morphologies, thus exerting a synergistic effect of supporting, stiffening, and pore preservation. Different from the traditional model of silica filling pores, this mechanism enables authigenic quartz precipitation from clay-derived silica in intergranular fractures, thereby enhancing the stability of microscopic pores and fractures in the reservoir.

     

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