Abstract:
With Rock-Eval 6 and Optkin kinetics software,the kinetics analysis on four types of kerogens of marine hydrocarbon source rocks in South China were carried out.The results showed that,in the similar maturity period,the hydrocarbon generation activation energy of kerogen was Ⅲ>Ⅱ
2>Ⅱ
1>Ⅰ;the ability of hydrocarbon generation was Ⅰ>Ⅱ
1>Ⅱ
2>Ⅲ;the span of generating effective hydrocarbon activation energy was ΔE
Ⅰ<15kJ/mol,15 kJ/mol<ΔE
Ⅱ1<20kJ/mol,20kJ/mol<ΔE
Ⅱ2<30 kJ/mol,ΔE
Ⅲ>30kJ/mol;the span of generating effective hydrocarbon temperature was ΔT
Ⅰ≤65℃,65℃≤ΔT
Ⅱ1≤75℃,75℃≤ΔT
Ⅱ2≤85℃,ΔT
Ⅲ≥110℃.The time of hydrocarbon generation conversion rate to reach 10% was Ⅲ<Ⅱ
2<Ⅱ
1<Ⅰ;and the type Ⅰ kerogen first reached to 90% conversion rate,and then the typeⅡ
1,type Ⅱ
2 and type Ⅲ of kerogen.The character of hydrocarbon generation activation energy distribution of kerogen was determined by their element composition and organic high molecular structure.The hydrocarbon generation speed of good marine source rocks was very fast.